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91.
92.
An oligosaccharide donor, acetylated sept-o-glucopyranose tetradecyl carbamate, was designed and synthesized. This compound could be easily linked to hydroxyl-containing compounds through an Oglycosidic bond. Characterization of all the oligosaccharide intermediates and the final product was thoroughly discussed. 相似文献
93.
94.
Gang Lian Xiao Zhang Lingling Zhu Qilong Wang 《Journal of solid state chemistry》2009,182(6):1326-1330
Phase transformation among different boron nitride (BN) phases in hydrothermal solution was investigated. It was found that hexagonal boron nitride (hBN) firstly formed in the solution at relatively low temperature (i.e., 220 °C). After that, a spot of hBN began to transform into wurtzite boron nitride (wBN) and cubic boron nitride (cBN) at 230 °C. More and more hBN converted into wBN and cBN with the increase in temperature, and this transformation process completed at 300 °C. In this paper, we have explained the mechanism of the above phase transformation by using a reported “puckering mechanism”. 相似文献
95.
The feasibility of a microcolumn electrophoresis technique was investigated with a 100 mm length, 2 mm I.D. fused-silica microcolumn packed with uniform quartz microncrystals prepared by hydrothermal synthesis. To evaluate the separation technique, tryptophan, phenylalanine and tyrosine were primarily separated by the microcolumn electrophoresis and detected at 216 nm without derivatization by an ordinary spectrophotometer. The separation conditions of the amino acids were optimized. With 1.5 mmol/L disodium phosphate buffer solution (pH 11.5) containing 25% (v/v) methanol and 10% (v/v) acetonitrile, the three amino acids were separated and the separation efficiency of tryptophan was 4.5 × 104 plates/m. The limits of detection were 0.035, 0.22 and 0.20 μmol/L, respectively. The sample capacity of the electrophoretic microcolumn achieved 35 μL. The proposed method was used to determine these amino acids in compound amino acid injection samples without derivatization. For the simplicity and portability of the microcolumn electrophoresis, it is studied as one of the high-performance separation techniques for an in situ and real-time electrokinetic flow analysis system. For its high detection sensitivity and large sample capacity, it can be developed for preparative electrophoresis. 相似文献
96.
The process of ultrasound-assisted emulsification-microextraction (USAEME) was successfully applied for the first time for the extraction and pre-concentration of trace cadmium from water samples, followed by flame atomic absorption spectrometry (FAAS). In the proposed approach, sodium diethyldithiocarbamate trihydrate solution (NaDDTC·3H2O) was used as a chelating agent and carbon tetrachloride was selected as extraction solvent. Some effective parameters on the microextraction and the complex formation were selected and optimized. These parameters included extraction solvent type as well as extraction volume, time, temperature, and pH, the amount of the chelating agent, and salt effect. Under optimum conditions, an enrichment factor of 95 was obtained from only 5.0 mL of water sample. The calibration graph was linear in the range of 10-600 μg L−1 with a detection limit of 0.91 μg L−1. The relative standard deviation (R.S.D) for ten replicate measurements of 50 and 500 μg L−1 of cadmium were 2.56 and 1.62%. This proposed method was successfully applied in the analysis of four real environmental water samples and good spiked recoveries over the range of 96.5-101.7% were obtained. 相似文献
97.
Robert J. Hinkle Yajing Lian Lee C. Speight Heather E. Stevenson Melissa M. Sprachman Lauren A. Katkish M. Christa Mattern 《Tetrahedron》2009,65(34):6834-9277
The rapid synthesis of cis-2,6-disubstituted dihydropyrans is achieved in a three-component, one-pot cascade reaction. BiBr3-mediated addition of ketene silyl acetals or silyl enol ethers to β,γ-unsaturated cis-4-trimethylsilyl-3-butenal provides a Mukaiyama aldol adduct containing a vinylsilane moiety tethered to a silyl ether. Addition of a second aldehyde initiates a domino sequence involving intermolecular addition followed by an intramolecular silyl-modified Sakurai (ISMS) reaction. Isolated yields of this one-pot reaction vary from 44 to 80% and all compounds were isolated as the cis-diastereomers (10 examples). 相似文献
98.
This paper addresses Gabor analysis on a discrete periodic set. Such a scenario can potentially find its applications in signal processing where signals may present on a union of disconnected discrete index sets. We focus on the Gabor systems generated by characteristic functions. A sufficient and necessary condition for a set to be a tight Gabor set in discrete periodic sets is obtained; discrete periodic sets admitting a tight Gabor set are also characterized; the perturbation of tight Gabor sets is investigated; an algorithm to determine whether a set is a tight Gabor set is presented. Furthermore, we prove that an arbitrary Gabor frame set can be represented as the union of a tight Gabor set and a Gabor Bessel set. 相似文献
99.
Qiaofang Lian 《Mathematical Methods in the Applied Sciences》2019,42(5):1335-1351
Recently, continuous‐time nonstationary Gabor (NSG) frames were introduced in adaptive signal analysis. They allow for efficient reconstruction with flexible sampling and varying window functions. In this paper, we focus on the existence and construction of NSG frames in the discrete‐time setting. We provide existence results for painless NSG frames and for NSG frames with fast decaying window functions. We also construct NSG frames with noncompactly supported window functions from a known painless NSG frame. Some examples are provided to illustrate the general theory. 相似文献
100.
A new-type UV light source(206 nm) was explored for the degradation of organic pollutants in wastewater for the first time.The degradation performances of triphenyltin chloride(TPTCl),dimethyl phthalate(DMP),as well as rhodamine B(RhB) were investigated.The results indicated that removal efficiency of 50 mg/L RhB,60 mg/L DMP and 120 mg/L TPTCl can reach 88.6%, 92.5%and 89.4%for 60 min,50 min and 75 min,respectively.By comparison of removal efficiency,we found 206 nm is superior to 253.7 nm UV in wastewat... 相似文献